Sharma, A and Kumar, Vinod and Sinha, Arun K (2006) A Chemoselective Hydrogenation of the Olefinic Bond of a,b-Unsaturated Carbonyl Compounds in Aqueous Medium under Microwave Irradiation. Advanced Synthesis Catalysis, 348 (3). pp. 354-360. ISSN 1615-4150

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Abstract

A microwave-assisted mild and ecofriendly catalytic transfer hydrogenation process was developed to reduce various a,b-unsaturated carbonyl compounds into the corresponding saturated carbonyl compounds in the presence of silica-supported palladium chloride as catalyst and a combination of MeOH/HCOOH/H2O (1 : 2 : 3) as hydrogen source within 22 – 55 minutes in moderate to excellent yields with 100% chemoselectivity

Item Type:	Article
Uncontrolled Keywords:	chemoselectivity; hydrogenation; microwave heating; a,b-unsaturated carbonyl compounds, water
Subjects:	Natural Product Chemistry
Divisions:	UNSPECIFIED
Depositing User:	Dr. Aparna Maitra Pati
Date Deposited:	27 Dec 2011 10:52
Last Modified:	13 Feb 2012 05:04
URI:	http://ihbt.csircentral.net/id/eprint/165

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