Sharma, A and Sharma, N and Kumar, R and Sharma, U K and Sinha, Arun K (2009) Water-promoted cascade synthesis of a-arylaldehydes from arylalkenes using N-halosuccinimides: an avenue for asymmetric oxidation using Cinchona organocatalysis. Chemical Communication, 35. pp. 5299-5301. ISSN 1359-7345
PDF
Restricted to Registered users only Download (1036Kb) |
Abstract
The direct oxidation of arylalkenes into a-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselectiveapproach is also explored to provide up to 30% ee in initial investigations.
Item Type: | Article |
---|---|
Uncontrolled Keywords: | Substituted Benzylic Aldehydes; Selective Synthesis; Ionic Liquids; Conversion; Ketones; Epoxides; Hydroformylation; Isomerization; Rearrangement; Epoxidation. |
Subjects: | Chemical Engineering |
Divisions: | UNSPECIFIED |
Depositing User: | Dr. Aparna Maitra Pati |
Date Deposited: | 27 Dec 2011 10:42 |
Last Modified: | 07 Feb 2012 11:44 |
URI: | http://ihbt.csircentral.net/id/eprint/137 |
Actions (login required)
View Item |