Sharma, A and Sharma, N and Kumar, R and Sharma, U K and Sinha, Arun K (2009) Water-promoted cascade synthesis of a-arylaldehydes from arylalkenes using N-halosuccinimides: an avenue for asymmetric oxidation using Cinchona organocatalysis. Chemical Communication, 35. pp. 5299-5301. ISSN 1359-7345

[img] PDF
Restricted to Registered users only

Download (1036Kb)

Abstract

The direct oxidation of arylalkenes into a-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselectiveapproach is also explored to provide up to 30% ee in initial investigations.

Item Type: Article
Uncontrolled Keywords: Substituted Benzylic Aldehydes; Selective Synthesis; Ionic Liquids; Conversion; Ketones; Epoxides; Hydroformylation; Isomerization; Rearrangement; Epoxidation.
Subjects: Chemical Engineering
Divisions: UNSPECIFIED
Depositing User: Dr. Aparna Maitra Pati
Date Deposited: 27 Dec 2011 10:42
Last Modified: 07 Feb 2012 11:44
URI: http://ihbt.csircentral.net/id/eprint/137

Actions (login required)

View Item View Item