Guha, Nitul Ranjan and Reddy, Chennayala Bal and Aggarwal, Nidhi and Sharma , Dharminder and Shil, Arun K and ------,, Bandna and Das, Pralay (2012) Solid-Supported Rhodium(0) Nano-/Microparticles: An Efficient Ligand-Free Heterogeneous Catalyst for Microwave-Assisted Suzuki–Miyaura Cross-Coupling Reaction. Journal of the Advanced Synthesis & Catalysis, 354. pp. 2911-2915.

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Abstract

Solid-supported nano- and microparticles of rhodium(0) (SS-Rh) were prepared and applied as a ligand free heterogeneous catalyst for Suzuki– Miyaura cross-coupling reaction with wide range of substrate scope. A hitherto unknown Rh-catalyzed Suzuki cross-coupling reaction of aldehyde and cyanohaloarenes was observed rather than the usual nucleophilic arylation.The catalyst can be removed by simple filtration and recycled upto twelve runs without any deterioration of activity.

Item Type:	Article
Uncontrolled Keywords:	heterogenous catalysts; ligand-free conditiosn; nano-/microparticles; solid-supported rhodium; Suzuki–Miyaura cross-coupling
Subjects:	Plant sciences Synthetic Chemistry
Divisions:	UNSPECIFIED
Depositing User:	Dr. Aparna Maitra Pati
Date Deposited:	06 Mar 2013 12:33
Last Modified:	06 Mar 2013 12:33
URI:	http://ihbt.csircentral.net/id/eprint/1305

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