Shil, Arun K and Sharma, Dharminder and Guha, Nitul Ranjan and Das, Pralay (2012) Solid supported Pd(0): an efficient recyclable heterogeneous catalyst for chemoselective reduction of nitroarenes. Tetrahedron Letters, 53. pp. 4858-4861.

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Solid supported palladium(0) (SS-Pd) catalyzed highly chemoselective reduction of nitroarenes to the corresponding anilines was accomplished under a milder reaction condition. This catalyst showed high compatibility with various reducing agents (NaBH4, Et3SiH, and NH2NH2∙H2O) and a large number of reducible functional groups such as sulfonamide, amides, carboxylic acid, ester, alcohol, halide, hetero cycle, nitrile, alkene, carbonyl, O-benzyl, and N-benzyl were tolerated. Most of the reactions were clean and high yielding. The SS-Pd catalyst could be recycled up to seven runs without significant loss of activity

Item Type: Article
Uncontrolled Keywords: Nitroarenes Chemoselective reduction Solid supported palladium Nano/micro particles Milder reducing source
Subjects: Natural Product Chemistry
Depositing User: Dr. Aparna Maitra Pati
Date Deposited: 03 Jan 2013 10:35
Last Modified: 03 Jan 2013 10:35

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